It sounds like you may have this problem.
www.fpaceforum.com

Locked Out of My Fuel Tank
Today I tried to put diesel in my car, but the silvery metal door, behind the yellow diesel cap, refused to move. I asked a mechanic at the gas station's body shop to come out and take a look to be sure that it wasn't me ;-) He could not get the nozzle to go in either, and asked his mechanic...